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( ): pharmazeutischewirkstoffe1982.djvu
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D: Amantadin (ratipharm)
Contenton® (SK Dauelsberg) PK-Merz® (Merz + Co.) Solu-Contenton® (SK Dauelsberg) Symmetrel® (Geigy)
F: Mantadix® (Theraplix) Trivaline® (Farmex)
GB: Symmetrel® (Geigy)
I: Mantadan® (De Angeli) J: Amazolon® (Sawai) USA: Symmetrel® (Endo)
Ambazon
539-21-9
6011-12-7
Monohydrat
Mund- und Rachen Chemotherapeuticum
p-benzoquinone amidinohydrazone thiosemicarbazone hydrate
C-NH-NH2
НгИ
Aminoguanidin
°=Q=o
p-Benzo-
chinon
C-NH
H2N
-n=0=°
Thiosemicarbazid
HN„
h2n'
^C-NH-N=^^>=N-NH-C^
NH2
DBP 965 723 (Bayer; Anm. 1953).
D: IversaJ® (Bayer) F: Iversai® (Bayer) GB: Iversal® (Bayer)
I: Primal® (Bayer) J; Iversal® (Bayer)
Ambenonium-chlorid
115-79-7 470-78-07
Base
Cholinesteraseinhibitor
[oxalylbis(iminoethylene)]bis[(o-chlorobenzyI)diethyI-ammonium chloride]
[H5C2)2N-CH2-CH2-NH2
/V,/V-Oi«thylethylendiamin
H5C2O OC2H5
}C-Cv
Д \s 0 0
Oxalsauredtethyl-
ester
(H5C2)2N~CH2-CH2-NH-C-C-NH-CH2-CH2-N(C2H5)2 0 0
2-Chtorbenzyl-
chlorid
C2Hs C;Hs
CH2 - N - CH2- CH2 - NH - С - C- NH - CH2 - CH2 - N- CH2-<^_^
^Н5 0 0 C2H5 r/
a
Ambenonium - chlond
Ambenonium-chlorid - Ambroxol - Ambusid A 35
pBP 1024517 (Sterling Drug; Anm. 1954; USA-Prior. 1953).
. USP 3 096 373 (Sterling Drug; ert. 2.7.1963; Anm. 1956).
A. P* Phillips, J. Am. Chem. Soc. 73,5822 (1951).
Oxamid-Zwischenprodukt:
USP2438 200 (du Pont; ert. 1948; Anm. 1946).
0; Mytelase® Tabletten (Winthrop) I: MyteJase® (Winthrop)
p. Mytelase® (Winthrop) J: Mytelase® (Nippon Shoji)
GB: Mytelase® (Winthrop) USA: Mytelase® (Winthrop)
AlTlbrOXOl 18683-91-5 Broncho-Sekretolyticum
/m/tf-4-[(2-amino-3,5-dibromobenzyl)amino]cyclohexanol NH-C
HO
-COCH3
Paracetamol (s. S. 684)
HO'
H ,—v NH-COCH3
Л-К
NH2
:o:
fran5-4-Amino-
cyclohexanol
7 ынг
2 -Amino-3,5-
dibrombenz-
atdehyd
NHl
NaBHt txier HCOOH
DOF1, 95(1976).
DOT 15, 523(1979).
DBP 1593 579 (Thomae; Anm. 10.5.1966).
DOS 2218 647 (Thomae; Anm. 18.4.1972).
DOS 2 223 193 (Thomae; Anm. 12.5.1972). /
J. Keck, Justus Liebigs Ann. Chem. 707,107 (1967).
D: Mucosolvan® (Thomae)
NH2
H j—у ,NH-CH2v
«Он у
Sr
Ambusid
3754-19-6
Diureticum; Antihypertensivum
Ari-allyl-4-chloro-6-[(3-hydroxy-2-buienyiidene)amino]-m-benzenedisulfonamide
36 A Ambusid - Amcinonid
С1у^/Нг
h2n-so2'^-'''So2-nh2
Oiethyicarbonat
clxx’
l-SO/^N
H2N-S02
H
S'm
02
1 NaH/DMF 2. Br-CHZ-CH=CH2
6-Ammo-4-chlorbenzol-
1,3-disulfonamid (vgl. Chiorothtazid-Synthese. S. 194)
H 115V. NaOH/90-l00eC
;.hc, aYY
H2N-so!->^As^CH2_CH=CH2 H2N-S02'^Sq2 - NH - CH2 -CH=CH2
2 - Allylaminosulfonyl - 4-aminosulfonyl-5-chloramlin
OH
I
1НзСО)2СН-СН=С-СНз; HCl Acetylacetaldehyddimethylacetal
OH
I
Clv^rv.N = CH-CH=C-CH3
H2N-S02'^^SO2- NH -CH2 -CH= CH2 Ambusid
USP 3 188 329 (Colgate-Palmolive; ert. 8.6.1965; Anm. 10.4.1962). Zwischenprodukte:
W. J. Close et aL, J. Am. Chem. Soc. 82,1132 (1960).
F: Hydrion® (Robert + Carriere)
Amcinonid 51022-69-6
(Triamcinolonacetat-cyciopentanoid)
Glucocorticoid
9-fluoro-11^16a,17,21-tetrahydrQxypregna-l,4-diene-3,20“dione cyclic 16,17-acetal with cyclopent-anone, 21-acetate
H0CH2V
HO^ (--OH
’ н T >-oh
HOCH2.
и
• 6
[НСЮ41
Cyclopentanon
(СНзСО)гО / Pyrtdin
CH3CO-O-CH2,
Amcinonid - Amfepramon - Amidephrin A 37
DOF3, 337 (1978); 4,376 (1979).
0OS 2 437 847 (American Cyanamid; Anm. 6.8.1974; USA-Prior. 17.8.1973). Belg-P 818 929 (American Cyanamid; Anm. 16.8.1974; USA-Prior. 17.8.1973).
p: Pendcort® (Lederle) j. Visderm® (Lederle)
USA: Cyclocort® (Lederle)
Amfepramon
(Diaethylpropion)
90-84-6
134-80-5
Hydrochlorid
Appetitzugler
2-(diethylamino)propiophenone
^-снг-снз
о
Propiophenon
q
C-CH-Br
o' in,
a-Brompropio-
phenon
Diethyl-
amin
Q
C2H5
C-CH-N О СНз C2HS Amfepramon
DOT 9,213 (1973).
USP 3 001910 (Temmler-Werke; ert. 26.9.1961; D-Prior. 16.4.1958).
D:
GB;
Regenon retard® (Temmler) Tenuate® (Merreil)
Derfon® (Lafon)-Komb.
Moderatan® (Tberanol)
Prefamone® (Dexo) Tenuate-Dospan® (Merrell-Toraude) Tenuate® (Merreil)
Tenuate Dospan® (Merreil)
i: dinea Valeas (Valeas)
diposlim® (Pharma Farm. Spec.) Magrene® (Ravasini)
Regenon® (Vanzini)
Tenuate Dospan® (Merreil) USA: Tenuate® (Merrell-National) Tepanil® (Riker)
Amidephrin 37571-84-9 Rhiniticum;
(Amidefrine) 1421-68-7 Methansulfonat Vasokonstrictor
3'-[ 1 -hydroxy-2-(methylarnino)ethyl]methane-sulfonanilide
H3C-S02CI ♦ <Р^с-снз
H2N 0 H3C-SO2-NH
Methansulfonyl- 3-Aminoaceto- 3-Metbylsulfonylamir>oacetopher>on
chlorid phenon
CHz-CeHs
Pi
•C-CH2-Br
чсн3
____CH2—CeHs
<f^>— c-ch2-n
N- Benzyl- \—/ II V
methylamir / 0 CH3
.. _ f и m«tryi«inni
H3C-SO2-NH НэС-502-NH
H:/Pd-C
- CH2 - NH - CH3
/ ли
h3c-so2-nh
Amidephrin
38 A Amidephrin - Amidotrizoesaure - Amikacin
FP-M 3 027 (Mead Johnson; Anm. 23.1.1963; USA-Prior. 24.1.1962,14.12.1962). GB: Dricol® (Bristol)
Amidotrizoesaure
(Diatrizoesaure; Natriumamidotrizoat; Sodium Diatrizoate)
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